جزییات کتاب
A contemporary compilation of recent achievements in organometallic chemistryThe prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC. Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover: Activation and Functionalization of Carbon Single Bonds and Small MoleculesOrganometallic Synthesis and CatalysisOrganometallic Polymerization CatalysisOrganometallic Polymers and MaterialsOrganometallic Chemistry and Sustainable EnergyBioorganometallic ChemistryOrganometallic ElectrochemistryChapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines. All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.Content: Chapter 1 Organometallic Complexes as Catalysts in Oxidation of CH Compounds (pages 1–13): Georgiy B. Shul'pinChapter 2 Toward Functionalization of Alkanes under Environmentally Benign Conditions (pages 15–25): Armando J. L. PombeiroChapter 3 Self‐Assembled Multicopper Complexes and Coordination Polymers for Oxidation and Hydrocarboxylation of Alkanes (pages 27–38): Alexander M. Kirillov, Marina V. Kirillova and Armando J. L. PombeiroChapter 4 Activation of C–O and C–F Bonds by Pincer–Iridium Complexes (pages 39–57): Jason Hackenberg, Karsten Krogh‐Jespersen and Alan S. GoldmanChapter 5 Functionalization of sp2 and sp3 Carbon Centers Catalyzed by Polyoxometalates and Metalloporphyrins (pages 59–71): Mário M. Q. Simões, Isabel C. M. S. Santos, Maria Graça P. M. S. Neves, Ana M. V. Cavaleiro and José A. S. CavaleiroChapter 6 Quasi‐Borinium Cation Based on Cobalt Bis(Dicarbollide): Its Lewis Acidity and C–H and C–X Bond Activation (pages 73–79): V. I. Bregadze, I. B. Sivaev, I. D. Kosenko, I. A. Lobanova, Z. A. Starikova and I. A. GodovikovChapter 7 Transition‐Metal‐Promoted Functionalization of Carboranes (pages 81–96): Zaozao Qiu and Zuowei XieChapter 8 Weak Interactions and M–H Bond Activation (pages 97–109): Elena Shubina, Natalia Belkova, Oleg Filippov and Lina EpsteinChapter 9 Complexes with Protic N‐Heterocyclic Carbene (NR,NH‐NHC) Ligands (pages 111–132): F. Ekkehardt HahnChapter 10 Cyclopentadienyl‐Functionalized N‐Heterocyclic Carbene Complexes of Iron and Nickel: Catalysts for Reductions (pages 133–143): Beatriz RoyoChapter 11 Palladium‐(Acyclic Diaminocarbene) Species as Alternative to Palladium‐(Nitrogen Heterocyclic Carbenes) in Cross‐Coupling Catalysis (pages 145–155): Vadim P. Boyarskiy, Konstantin V. Luzyanin and Vadim Yu. KukushkinChapter 12 Synthesis of Metallocenes Via Metathesis in Metal Coordination Spheres (pages 157–170): Antoni Pietrzykowski and WŁodzimierz BuchowiczChapter 13 Metal‐Mediated [2+3] Dipolar Cycloaddition to Substrates with CN Triple Bond: Recent Advances (pages 171–183): Konstantin V. Luzyanin and Maxim L. KuznetsovChapter 14 Coordination Chemistry of Oxazoline/Thiazoline‐Based P,N Ligands (pages 185–198): Shuanming Zhang, Roberto Pattacini and Pierre BraunsteinChapter 15 “Click” Copper Catalyzed Azide–Alkyne Cycloaddition (CUAAC) in Aqueous Medium (pages 199–206): Joaquín García‐Álvarez and José GimenoChapter 16 Organogold Catalysis: Homogeneous Gold‐Catalyzed Transformations for a Golden Jubilee (pages 207–225): Fabien GagoszChapter 17 Vanadium(IV) Complexes Derived from Aromatic O‐Hydroxyaldehydes and Tyrosine Derivatives: Catalytic Evaluation in Sulfoxidations (pages 227–232): João Costa Pessoa, Isabel Correia and Pedro AdãoChapter 18 Microwave‐Assisted Catalytic Oxidation of Alcohols to Carbonyl Compounds (pages 233–245): Yauhen Yu. Karabach, Maximilian N. Kopylovich, Kamran T. Mahmudov and Armando J. L. PombeiroChapter 19 Oxidation of Glycerol with Hydrogen Peroxide Catalyzed by Metal Complexes (pages 247–257): Dalmo Mandelli, Wagner A. Carvalho, Lidia S. Shul'pina, Alexander M. Kirillov, Marina V. Kirillova, Armando J. L. Pombeiro and Georgiy B. Shul'pinChapter 20 Involvement of an Acetato Ligand in the Reductive Elimination Step of the Rhodium‐Catalyzed Methanol Carbonylation (pages 259–268): Duc Hanh Nguyen, Nicolas Lassauque, Thomas Davin, Laurent Maron, Carole Le Berre, Philippe Serp and Philippe KalckChapter 21 Half‐Sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole‐Based Ligands (pages 269–284): Claudio Pettinari, Riccardo Pettinari, Corrado Di Nicola and Fabio MarchettiChapter 22 Carbon–Scorpionate Complexes in Oxidation Catalysis (pages 285–294): Luísa M. D. R. S. Martins and Armando J. L. PombeiroChapter 23 Toward Chemoselective Bioconjugative Desulfitative Catalysis (pages 295–303): Lanny S. Liebeskind and Ethel C. Garnier‐AmblardChapter 24 Sulfoxide Redox Chemistry with Molybdenum Catalysts (pages 305–314): Maria José Calhorda and Luis F. VeirosChapter 25 A New Family of Zirconium Complexes Anchored by Dianionic Cyclam‐Based Ligands: Syntheses, Structures, and Catalytic Applications (pages 315–323): Ana M. Martins, Rui F. Munhá, Luis G. Alves and Shanmuga BharathiChapter 26 Metal–Organo Multicatalysis: An Emerging Concept (pages 325–342): Alexandre F. Trindade, João N. Rosa, Fábio M. F. Santos and Pedro M. P. GoisChapter 27 Coordinative Chain Transfer Polymerization and Copolymerization by Means of Rare Earth Organometallic Catalysts for the Synthesis of Tailor‐Made Polymers (pages 343–358): Marc Visseaux, Thomas Chenal and Philippe ZinckChapter 28 Charge‐Neutral and Cationic Complexes of Large Alkaline Earths for Ring‐Opening Polymerization and Fine Chemicals Catalysis (pages 359–378): Jean‐François Carpentier, Bo Liu and Yann SarazinChapter 29 Organometallic Polymers (pages 379–405): Manuel Serrano‐Ruiz, Franco Scalambra and Antonio RomerosaChapter 30 From Serendipity to Porosity:Synthesis and Reactivity of Coordination Polymers Based on Copper Trinuclear Triangular Motifs (pages 407–419): Luciano PandolfoChapter 31 Organometallic Nanoparticles (pages 421–436): Patricia Lara, Karine Philippot, Lise‐Marie Lacroix, Sébastien Lachaize, Nikos Liakakos, Katerina Soulantica and Bruno ChaudretChapter 32 Organometallic Compounds in the Synthesis of New Materials: Old Ligands, New Tricks (pages 437–444): Piotr Sobota and Łukasz JohnChapter 33 The Role of Organometallic Complexes in the Synthesis of Shaped Carbon Materials (pages 445–458): Neil J. Coville and Edward N. NxumaloChapter 34 Metal Catalysis in Fullerene Chemistry (pages 459–472): Salvatore Filippone, Enrique E. Maroto, Ángel Martín‐Domenech and Nazario MartínChapter 35 Organometallic Complexes of Sumanene (pages 473–483): Toru Amaya and Toshikazu HiraoChapter 36 Advances in Luminescent Tetracoordinate Organoboron Compounds (pages 485–492): D. Suresh and Pedro T. GomesChapter 37 Mechanochemistry: A Tool in the Synthesis of Catalysts, Metallodrugs, and Metallopharmaceuticals (pages 493–499): Vânia André, Clara S. B. Gomes and M. Teresa DuarteChapter 38 Organometallic Compounds for Dye‐Sensitized Solar Cells (DSSC) (pages 501–511): Delele W. Ayele, Wei‐Nein Su, John Rick, Hung‐Ming Chen, Chun‐Jern Pan, Nibret G. Akalework and Bing‐Joe HwangChapter 39 Synthetic Photosynthesis for the Conversion of Large Volumes of Carbon Dioxide into Energy‐Rich Molecules: Saving Fossil Fuels by Recycling Carbon (pages 513–527): Michele Aresta and Angela DibenedettoChapter 40 Ionic Liquids for Hydrogen Storage: Opportunities for Organometallic Chemistry (pages 529–541): Martin H. G. Prechtl and Sebastian SahlerChapter 41 Metal Carbonyls for Co‐Based Therapies: Challenges and Successes (pages 543–561): Carlos C. Romão and Helena L. A. VieiraChapter 42 The Ferrocifen Family as Potent and Selective Antitumor Compounds: Mechanisms of Action (pages 563–580): Gérard Jaouen and Siden TopChapter 43 On the Track to Cancer Therapy: Paving New Ways with Ruthenium Organometallics (pages 581–587): Tânia S. Morais and M. Helena GarciaChapter 44 Organometallic Chemistry of Rhenium and Technetium Fueled by Biomedical Applications (pages 589–604): António Paulo, Goreti Ribeiro Morais and Isabel SantosChapter 45 Metal‐Based Indolobenzazepines and Indoloquinolines: From Moderate CDK Inhibitors to Potential Antitumor Drugs (pages 605–617): Michael F. Primik, Lukas K. Filak and Vladimir B. ArionChapter 46 Metal‐Based Chelates and Nanosystems as MRI Contrast Agents (pages 619–630): Sara Figueiredo and Carlos F. G. C. GeraldesChapter 47 Electrochemistry and Supramolecular Interactions of “Ferrocifen” Anticancer Drugs with Cyclodextrins and Lipid Bilayers: An Electrochemical Overview (pages 631–651): Olivier Buriez, Eric Labbé and Christian AmatoreChapter 48 Electrochemistry of Fischer Aminocarbene Complexes: Effects of Structure on Redox Properties, Electron Distribution, and Reaction Mechanisms (pages 653–665): Jiří Ludvík and Irena HoskovcováChapter 49 Electron Transfer‐Induced Coordination Changes in Organometallic Complexes with Noninnocent Hemilabile Ligands (pages 667–675): Wolfgang Kaim, Martina Bubrin and Ralph HübnerChapter 50 Redox Potential–Structure Relationships and Parameterization in Characterization and Identification of Organometallic Compounds (pages 677–690): M. Fátima C. Guedes da Silva and Armando J. L. PombeiroChapter 51 Endohedral Metallofullerenes Today: More and More Versatile Ships in Multiform Bottles—Electrochemistry of X‐Ray Characterized Monometallofullerenes (pages 691–702): Fabrizia Fabrizi de Biani and Piero Zanello