دانلود کتاب Inorganic Reactions and Methods: Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 4), Volume 12B

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.Content: Chapter 5.8.1 Introduction (pages 2–18): A. P. Hagen and G. B. YoungChapter 5.8.2.8.2 ??Allyl Metal Complexes by Reaction with the Corresponding Metal Halides (pages 18–35): S. S. Wreford, R. Pankayatselvan and K. M. NicholasChapter 5.8.2.8.3 ?5??Cyclopentadienyl Metal Complexes by Reaction with the Corresponding Metal Halides (pages 35–68): R. T. BakerChapter 5.8.2.8.4 ?1 ??Acyls from Alkali?Metal Carbanions and Metal Carbonyls (pages 68–72): E. RoseneergChapter 5.8.2.8.5 ?1 ??Acyl and Carbene Complexes by Reaction With Corresponding Metal–Carbonyl Complexes (pages 72–86): E. O. Fischer and H. FischerChapter 5.8.2.8.6 ?1 ??Cyanide Complexes (pages 87–104): L. M. VallarinoChapter 5.8.2.8.7 Ylide Complexes of the Transition Metals by Treating the Ylide with Transition?Metal Halide (pages 104–107): W. C. KaskaChapter 5.8.2.9 From Organic Halides, Tosylates and Acetates (pages 108–121): E. RoseneergChapter 5.8.2.9.2 (?1)???Alkyl–, ?Aryl–, and ?Acyl–Metal Complexes by Reaction with Metal?Complex Anions (pages 121–125): P. M. TreichelChapter 5.8.2.9.3 ?1 ??Alkyl–, ?Aryl–, Acyl– and Silyl Metal Complexes by Reaction of Metal?Atom Vapors (pages 125–131): K. J. KlabundeChapter 5.8.2.9.4 ?3 ??Allyl Transition?Metal Complexes by Oxidative Addition (pages 131–153): K. Zetterberg, B. Akermark and J.?E. BackvallChapter 5.8.2.9.5 ?4 ??Cyclobutadienyl Complexes from 3,4?Dihalocyclobutenes (pages 153–156): E. RosenbergChapter 5.8.2.10 From Aldehydes (pages 156–159): J. W. SuggsChapter 5.8.2.11 From Other Organometallics (pages 160–167): R. C. Larock Chapter 5.8.2.11.2 by Transmetallation from Mercury (pages 167–176): R. C. LarockChapter 5.8.2.11.3 by Transmetallation from Other Metal Organometallics to Metal Halides (pages 176–183): E. NegishiChapter 5.8.2.12 From Carbon Monoxide (pages 183–190): G. P. Chiusoli and M. CatellaniChapter 5.8.2.12.2 Carbonyl Complexes by Ligand?Exchange Reactions (pages 190–197): G. P. Chiusoli and M. CatellaniChapter 5.8.2.12.3 ?1 ??Acyl Complexes by Insertion of Co in ??Alkyl Complexes (pages 197–201): F. CalderazzoChapter 5.8.2.12.4 Carbamoyl Complexes by Reaction of Metal Carbonyls with Amines (pages 201–204): P. M. TreichelChapter 5.8.2.12.5 Alkoxycarbonyl Complexes by Reaction of Metal Carbonyls with Alcohols and Alkoxides (pages 204–206): P. M. TreichelChapter 5.8.2.13 From Carbon Disulfide, Thioacid Chlorides, or Carbon Diselenide (pages 206–209): I. S. ButlerChapter 5.8.2.14 From Carbon Dioxide (pages 209–212): D. M. RoundhillChapter 5.8.2.15 From Isonitriles (pages 213–215): H. YamazakiChapter 5.8.2.15.2 Iminoacyl Complexes by Isonitrile Insertion (pages 216–218): Y. YamamotoChapter 5.8.2.16 From Miscellaneous Species (pages 218–221): E. O. Fischer and U. SchubertChapter 5.8.2.16.2 Carbyne Complexes by Deprotonation of Cationic Carbene Complexes (pages 222–224): C. M. LukehartChapter 5.8.2.16.3 Carbyne Complexes by Dehalogenation of Chlorocarbene Complexes (pages 224–225): C. M. LukehartChapter 5.8.2.16.4 By Metal?Atom and Related Reactions (pages 225–227): K. J. KlabundeChapter 5.8.3 The Formation of the Silicon?Transition and Inner Transition?Metal Bond (page 227): S. A. A. KnoxChapter 5.8.3.2.1 By Reaction with a Transition? or Inner Transition?Metal Halide Derivative in the Presence of Triethylamine (pages 227–228): S. A. R. KnoxChapter 5.8.3.2.2 By Reaction with a Transition? or Inner Transition?Metal Hydride Complex (pages 228–229): S. A. R. KnoxChapter 5.8.3.2.3 By Reaction with a Mononuclear Transition? or Inner Transition?Metal Carbonyl in the Presence of Ultraviolet Radiation (pages 229–230): S. A. R. KnoxChapter 5.8.3.2.4 By Reaction with Di? or Trinuclear Transition? or Inner Transition?Metal Carbonyl Complexes (pages 230–234): S. A. R. KnoxChapter 5.8.3.2.5 By Oxidative Addition to a Low?Valent Transition? or Inner Transition?Metal Complex (pages 234–237): S. A. R. KnoxChapter 5.8.3.2.6 By Reaction with a Group?IVb Transition? or Inner Transition?Metal Derivative (pages 237–239): S. A. R. KnoxChapter 5.8.3.3 From Silicon Halides (pages 239–242): S. A. R. KnoxChapter 5.8.3.4 From Silyl?Alkali Metal Reagents (pages 242–243): S. A. R. KnoxChapter 5.8.3.4.2 By Reaction with a Low?Valent Transition? or Inner Transition?Metal Complex (page 243): S. A. R. KnoxChapter 5.8.3.5 From Bis(Silyl) Mercurials (pages 244–245): S. A. R. KnoxChapter 5.8.3.5.2 By Reaction with Low?Valent Transition? or Inner Transition?Metal Complexes (page 245): S. A. R. KnoxChapter 5.8.3.6 Miscellaneous Reactions (pages 245–246): S. A. R. KnoxChapter 5.8.3.6.2 From Sila? and 1,3?Disilacyclobutanes by Reaction With Fe2(Co)9 (pages 246–248): S. A. R. Knox Chapter 5.8.3.6.3 By Reaction of SiR4 with a Low?Valent Transition? or Inner Transition?Metal Complex (page 248): S. A. R. KnoxChapter 5.8.3.6.4 From Silyl Amides by Reaction with a Transition? or Inner Transition?Metal Hydride (pages 248–249): S. A. R. KnoxChapter 5.8.4 the Formation of the Germanium–Transition and Inner?Transtion Metal Bond (page 249): K. M. MackayChapter 5.8.4.1 From the Elements (pages 249–250): K. M. MackayChapter 5.8.4.2 From Germanium Hydrides (pages 250–255): K. M. MackayChapter 5.8.4.2.2 By Oxidative Addition to Low?Coordinate Transition?Metal Complexes (pages 255–258): K. M. MackayChapter 5.8.4.2.3 By Reaction with Transition? or Inner?Transition?Metal Halide, Hydride and Related Complexes (pages 258–260): K. M. MackayChapter 5.8.4.2.4 By Proton Abstraction of Hydrogen to form Unsaturated Ge–Metal Bonds (pages 260–261): K. M. MackayChapter 5.8.4.2.5 Miscellaneous Reactions of the Ge—H Bond (pages 261–262): K. M. Mackay Chapter 5.8.4.3 From Germanium Halides (pages 262–266): K. M. MackayChapter 5.8.4.3.2 By Reaction of Germanium Tetrahalides with Neutral Mononuclear Metal Carbonyls and Related Species (pages 266–267): K. M. MackayChapter 5.8.4.3.3 By Reaction with a Silyl–Transition? or Inner?Transition?Metal–Metal Complex (page 268): K. M. MackayChapter 5.8.4.4 From Germyl–Alkali?Metal Reagents (pages 268–271): K. M. MackayChapter 5.8.4.5 From Bis(Germyl)Mercury or ?Cadmium [Note: these Substances are Highly Toxic and Must be Handled with Care.] (pages 271–272): K. M. MackayChapter 5.8.4.5.2 By Reaction with Low?Valent Transition? or Inner?Transition?Metal Complexes (pages 272–273): K. M. MackayChapter 5.8.4.5.3 By Reaction with Binuclear Metal Carbonyls (page 273): K. M. MackayChapter 5.8.4.6 From Germanium(II) (pages 273–275): K. M. MackayChapter 5.8.4.6.2 By use of [Gex3]? (pages 275–276): K. M. MackayChapter 5.8.4.7 From Germyl Amides by Reaction with Transition? or Inner?Transition?Metal Hydrides (pages 276–277): K. M. MackayChapter 5.8.4.8 From Species Containing Ge Bonded to Unsaturated Ligands (page 277): K. M. MackayChapter 5.8.5 The Formation of the Tin–Transition? or Inner Transition?Metal Bond (pages 277–278): K. M. MackayChapter 5.8.5.1 From the Elements (page 278): M. J. NewlandsChapter 5.8.5.2 From Organotin Hydrides (pages 278–279): M. J. NewlandsChapter 5.8.5.2.2 By Reaction with Polynuclear Transition? or Inner Transition?Metal Carbonyl Derivatives (page 279): M. J. NewlandsChapter 5.8.5.2.3 By Reaction with Transition? or Inner Transition?Metal?Halide and ?Amide Complexes (pages 279–280): M. J. NewlandsChapter 5.8.5.2.4 By Reaction with Transition?Metal or Inner Transition?Metal?Olefin Complexes (page 280): M. J. NewlandsChapter 5.8.5.2.5 By Reaction with Silyl?Transition?Metal or ?Inner Transition?Metal Complexes (page 280): M. J. NewlandsChapter 5.8.5.3 From Tin(IV) and Organotin Halides (pages 280–282): M. J. NewlandsChapter 5.8.5.3.2 By Reaction with a Transition? or Inner Transition?Metal?Hydride Complex (page 283): M. J. NewlandsChapter 5.8.5.3.3 By Reaction with a Transition? or Inner Transition?Metal?Mercury Complex (page 283): M. J. NewlandsChapter 5.8.5.3.4 By Reaction with Mononuclear Transition?Metal Carbonyl Derivatives (pages 283–284): M. J. NewlandsChapter 5.8.5.3.5 By Reaction with Polynuclear Transition? or Inner Transition?Metal Carbonyl Derivatives (pages 284–285): M. J. NewlandsChapter 5.8.5.3.6 By Reaction with Transition? or Inner Transition?Metal?Olefin Complexes and Other Complexes with Readily Displaceable Ligands (pages 285–286): M. J. NewlandsChapter 5.8.5.4 From Organotin?Nitrogen Compounds (page 286): M. J. NewlandsChapter 5.8.5.4.2 By Reaction of an Organotin Azide with a Transition? or Inner Transition?Metal?Hydride Complex (page 286): M. J. NewlandsChapter 5.8.5.4.3 By Reaction of Organotin?Nitrogen Compounds with Other Complexes of the Transition or Inner Transition Metals (pages 286–287): M. J. NewlandsChapter 5.8.5.5 From Stannyl?Active Metal Reagents (pages 287–288): M. J. NewlandsChapter 5.8.5.6 From Tetraorganotin Compounds (page 288): M. J. NewlandsChapter 5.8.5.6.2 By Reaction of Vinyitin Compounds with Transition? or Inner Transition?Metal?Carbonyl Complexes (page 288): M. J. NewlandsChapter 5.8.5.6.3 By Reaction of Allyltin Compound with Transition? or Inner Transition?Metal?Carbonyl and Other Complexes (page 289): M. J. NewlandsChapter 5.8.5.6.4 By Reaction of Aryltin Compound and Cyclopentadienyltin Compounds with Transition? or Inner Transition?Metal?Carbonyl and Other Complexes (pages 289–290): M. J. NewlandsChapter 5.8.5.7 From Hexalkylditin Compounds by Reaction with Low?Valent Transition? or Inner Transition?Metal Complexes (page 290): M. J. NewlandsChapter 5.8.5.8 From Tin(II) Halides and Related Tin (II) Compounds (pages 290–293): M. J. NewlandsChapter 5.8.5.8.2 By Reaction with a Transition? or Inner Transition?Metal?Metal Alkyl or Hydride Complex (page 293): M. J. NewlandsChapter 5.8.5.8.3 By Reaction with Transition? or Inner Transition?Metal?Carbonyl and Similar Complexes (pages 293–294): M. J. NewlandsChapter 5.8.5.8.4 Miscellaneous Reactions of Sn(II) Compounds (pages 294–295): M. J. NewlandsChapter 5.8.6 The Formation of the Lead?Transition or Inner Transition?Metal Bond (page 295): M. J. NewlandsChapter 5.8.6.1 From the Elements (page 295): M. J. NewlandsChapter 5.8.6.3 From Organolead Hydroxides and Other Organolead Salts (page 297): M. J. NewlandsChapter 5.8.6.4 From Organolead Anion Reagents by Reaction with Transition? or Inner Transition?Metal?Halide Complexes (page 297): M. J. NewlandsChapter 5.8.6.5 By Other Methods (page 297): M. J. NewlandsChapter 5.9 The Formation of the Group IVB?Group 0 Element Bond (page 298): N. BartlettChapter 5.10 The Formation of Carbides, Silicides and Germides (pages 299–300): A. P. Hagen and E. K. StormsChapter 5.10.2.1 Formation of Group I Carbides (page 300): E. K. StormsChapter 5.10.2.1.1 Lithium Carbides (pages 300–301): E. K. StormsChapter 5.10.2.1.2 Sodium Carbides (page 301): E. K. StormsChapter 5.10.2.1.3 Potassium, Rubidium and Cesium Carbides (page 302): E. K. StormsChapter 5.10.2.2 Formation of the Group?II Carbides (page 302): E. K. StormsChapter 5.10.2.2.2 Magnesium Carbide (pages 302–303): E. K. StormsChapter 5.10.2.2.3 Calcium Carbide (page 303): E. K. StormsChapter 5.10.2.2.4 Strontium Carbide (pages 303–304): E. K. StormsChapter 5.10.2.2.5 Barium Carbide (page 304): E. K. StormsChapter 5.10.2.3 Formation of Group?IIIb Carbides (page 304): E. K. StormsChapter 5.10.2.3.1 Boron Carbides (pages 304–305): E. K. StormsChapter 5.10.2.3.2 Aluminum Carbide (page 305): E. K. StormsChapter 5.10.2.4 Formation of Group?IVb Carbides (pages 305–306): E. K. StormsChapter 5.10.2.5 Formation of SC, Y and LA Carbides (pages 306–307): E. K. StormsChapter 5.10.2.5.2 Yttrium Carbides (page 307): E. K. StormsChapter 5.10.2.5.3 Lanthanum Carbides (pages 307–308): E. K. StormsChapter 5.10.2.6 Formation of the Rare?Earth Carbides (page 308): E. K. StormsChapter 5.10.2.7 Actinide Carbides (pages 308–309): E. K. StormsChapter 5.10.2.7.2 Uranium Carbides (pages 309–310): E. K. StormsChapter 5.10.2.7.3 Plutonium Carbides (page 310): E. K. StormsChapter 5.10.2.8 The Formation of Transition?Metal Carbides (pages 310–311): E. K. StormsChapter 5.10.2.8.1 Titanium, Zirconium and Hafnium Carbides (pages 311–312): E. K. StormsChapter 5.10.2.8.2 Vanadium, Niobium and Tantalum Carbides (pages 312–313): E. K. StormsChapter 5.10.2.8.3 Chromium Carbides (pages 313–314): E. K. StormsChapter 5.10.2.8.4 Molybdenum Carbides (page 314): E. K. StormsChapter 5.10.2.8.5 Tungsten Carbides (pages 314–315): E. K. StormsChapter 5.10.2.8.6 Manganese Carbide (page 315): E. K. StormsChapter 5.10.2.8.7 Technetium Carbide (page 316): E. K. StormsChapter 5.10.2.8.8 Rhenium Carbide (page 316): E. K. StormsChapter 5.10.2.9 Formation of Group?VIII Carbides (pages 316–317): E. K. StormsChapter 5.10.2.9.2 Cobalt Carbides (page 317): E. K. StormsChapter 5.10.2.9.3 Nickel Carbides (page 318): E. K. StormsChapter 5.10.2.9.4 Ruthenium and Osmium Carbide (page 318): E. K. StormsChapter 5.10.2.9.5 Carbides of Rhodium, Palladium, Iridium, and Platinum (page 318): E. K. StormsChapter 5.10.2.10 The Formation of Complex Carbides (pages 318–319): E. K. StormsChapter 5.10.2.10.2 Transition Metal?Nonmetal?Carbon Carbides (pages 319–321): H. NowotnyChapter 5.10.2.10.3 Multicomponent Carbides (pages 321–323): P. EttmayerChapter 5.10.3 The Formation of Silicides (pages 323–324): R. Pretorius and J. J. CruywagenChapter 5.10.3.1 Of Groups IA and IIA (pages 325–326): R. Pretorius and J. J. CruywagonChapter 5.10.3.2 Of Transition?, Inner?Transition and Group?IB and ?IIB Metal Silicides (pages 326–338): R. Pretorius and J. J. CruywagenChapter 5.10.3.2.2 Of Inner?Transition?Metal Silicides (pages 338–339): R. Pretorius and J. J. CruywagenChapter 5.10.3.2.3 Of Silicides of Groups IB and IIB (page 339): R. Pretorius and J. J. CruywagenChapter 5.10.3.3 Of Ternary and Multicomponent Silicides (pages 339–340): R. Pretorius and J. J. CruywagenChapter 5.10.4 The Formation of Germanides (pages 340–343): R. Pretorius and J. J. CruywagenChapter 5.10.4.2 Formation of Ternary Germanides (page 343): R. Pretorius and J. J. Cruywagen